Fenton试剂催化降解有机废水的研究进展
摘要：Fenton技术作为一门高级氧化技术(AOPs),在降解废水中的有机污染物这一领域极具优势,是一种非常理想的有机污水处理工艺,另外,在基于普通Fenton技术上延伸出来的新的类Fenton技术、电Fenton(EF)、光Fenton技术等,与传统的Fenton技术相比较,也各有精进之处。综述了Fenton及类Fenton、电Fenton、光Fenton等技术的催化作用机理、影响因素、技术障碍、技术突破以及最新研究动态。
关键词：Fenton试剂催化降解机理有机物氧化水处理
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参考文献参考文献
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[28] NAHID H,AYOUB K J.Comparison of photo-Fenton,O3/H2O2/UV and photocatalytic processes for the treatment of gray water[J].Ecotoxicology and Environmental Safety,2018,161:683-690．
[29] AMBIKA S,DEVASENA M,NAMBI I M.Assessment of meso scale zero valent iron catalyzed Fenton reaction in continuous-flow porous media for sustainable groundwater remediation[J].Chemical Engineering Journal,2018,334(2):264-272．
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[31] JosAlejandro Ortega-Mndez,JosAlberto Herrera-Melin,Javier Araa,et al.Performance and Economic Assessment of the Treatment of Phenol with TiO2Photocatalysis,PhotoFenton,Biological Aerated Filter,and Wetland Reactors[J].Chemical Engineering&Technology,2017,40 (6):1165-1175．
[32] PLIEGO G,GARCIA-MU1OZ P,ZAZO J A,et al.Improving the Fenton process by visible LED irradiation[J].Environmental Science and Pollution Research,2016,23(23):23449-23455．
[33] Mohamed Gar Alalm,Ahmed Tawfik,Shinichi Ookawara.Investigation of optimum conditions and costs estimation for degradation of phenol by solar photo-Fenton process[J].Applied Water Science,2017,1(7):375-382．
[34] NOGUEIRA K R B,NASCIMENTO C A O,GUARDANIR,et al..Teixeira.Feasibility study of a solar reactor for phenol treatment by the photo-fenton process in aqueous solution[J].Chemical Engineering&Technology,2012,35(12):2125-2132．
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[38] LIU Y Y,Xuemin,et al.Alignedα-FeOOH nanorods anchored on a graphene oxide-carbon nanotubes aerogel can serve as an effective Fenton-like oxidation catalyst[J].Applied Catalysis B Environmental,2017,213(9):74-86．
[39] DEMARCHIS L,MINELLA M,NISTICòR,et al.PhotoFenton reaction in the presence of morphologically controlled hematite as iron source[J].Journal of Photochemistry&Photobiology A Chemistry,2017,307-308(7-8):99-107．
[40] Lv,Qiang,Lu,et al.Preparation of magnetic zeolite gammaFe2O3/TS-1 with core/shell structure and application in photocatalytic degradation[J].Microporous&Mesoporous Materials,2015,203(2):202-207．
[41] Len,María Andrea De,Rodríguez,Mayra,Marchetti S G,et al.Raw montmorillonite modified with iron for photoFenton processes:influence of iron content on textural,structural and catalytic properties[J].Journal of Environmental Chemical Engineering,2017,5 (5):4742-4750．
[42] Sun,Kai,Changgeng.Controllable synthesis of coralloid Fe3O4nanoclusters in an ionic liquid for catalytic applications[J].Crystengcomm,2016,18(5):714-720．
[43] ZHANG S,LIANG S,WANG X,et al.Trinuclear iron cluster intercalated montmorillonite catalyst:Microstructure and photo-Fenton performance[J].Catalysis Today,2011,175(1):362-369．
[44] PARIDA K M,PRADHAN A C.Femeso-Al2O3:An Efficient Photo-Fenton Catalyst for the Adsorptive Degradation of Phenol[J].Industrial&Engineering Chemistry Research,2010,49(18):8310-8318．
[45] 刘保锋,王丽,童晨．树脂负载Fe(Ⅲ)/Cu(Ⅱ)非均相光Fenton体系降解罗丹明B模拟废水研究[J]．湖北农业科学,2017,56(18):3461-3467．
[46] 王维明,张冉,王树涛,等．非均相光降解-氯酚的研究[J]．安全与环境学报,2013,13(1):31-35．
[47] LIANG C,LIU Y,LI K,et al.Heterogeneous photo-Fenton degradation of organic pollutants with amorphous Fe-Znoxide/hydrochar under visible light irradiation[J].Separation&Purification Technology,2017,188(7):105-111．
[48] SANTOS A J D,LIMA M D D,SILVA D R D,et al.Influence of the water hardness on the performance of electro-Fenton approach:Decolorization and mineralization of Eriochrome Black T[J].Electrochimica Acta,2016,208(8):156-163．
[49] MOREIRA F C,BOAVENTURA R A R,BRILLAS E,et al.Electrochemical advanced oxidation processes:A review on their application to synthetic and real wastewaters[J].Applied Catalysis B Environmental,2016,202(4):217-261．
[50] XIA G,LU Y,XU H.Electrogeneration of hydrogen peroxide for electro-Fenton via oxygen reduction using polyacrylonitrile-based carbon fiber brush cathode[J].Electrochimica Acta,2015,158(Complete):390-396．
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[52] MOUSSET E,WANG Z,HAMMAKER J,et al.Electrocatalytic phenol degradation by a novel nanostructured carbon fiber brush cathode coated with graphene ink[J].Electrochimica Acta,2017,258(20):607-617．
[53] DENG F,GARCIA-RODRIGUEZ O,OLVERA-VARGASH,et al.Iron-foam as a heterogeneous catalyst in the presence of tripolyphosphate electrolyte for improving electro-Fenton oxidation capability[J].Electrochimica Acta,2018,272(10):176-183．
[54] DENG F,OLVERA-VARGAS H,GARCIA-RODRIGUEZO,et al.The synergistic effect of nickel-iron-foam and tripolyphosphate for enhancing the electro-Fenton process at circum-neutral pH[J].Chemosphere,2018,201(6):687-696．
[55] 陈婷,冯波,梁静．超声波协同紫外光催化Fenton反应法降解对氯苯酚废水[J]．基因组学与应用生物学,2013,0(3):379-383．
[56] MOUSSET E,HUANG WEIQI V,BRANDON F Y K,et al.A new 3D-printed photoelectrocatalytic reactor combining the benefits of a transparent electrode and of the Fenton reaction for advanced wastewater treatment[J].Journal of Materials Chemistry A,2017,5(47):24951-24964．
[57] 王斯琪,郑璐．US/三维电极电Fenton体系处理孔雀石绿废水的试验研究[J]．建筑与预算,2019(4):59-62.
[1] BABUPONNUSAMI A,MUTHUKUMAR K.A review on Fenton and improvements to the Fenton process for wastewater treatment[J].Journal of Environmental Chemical Engineering,2014,2(1):557-572．
[2] 赵莉．Fenton氧化技术在高浓度有机废水预处理中的应用状况探究[J]．绿色环保建材,2019,2(9):40-41．
[3] MOREIRA F C,BOAVENTURA R A R,BRILLAS E,et al.Electrochemical advanced oxidation processes:A review on their application to synthetic and real wastewaters[J].Applied Catalysis B Environmental,2016,2(2):217-261．
[4] BABUPONNUSAMI A,MUTHUKUMAR K.A review on Fenton and improvements to the Fenton process for wastewater treatment[J].Journal of Environmental Chemical Engineering,2014,2(1):557-572．
[5] GARCIA-SEGURA S,BELLOTINDOS L M,HUANG YH,et al.Fluidized-bed Fenton process as alternative wastewater treatment technology-A review[J].Journal of the Taiwan Institute of Chemical Engineers,2016,67(10):211-225．
[6] BOONRATTANAKIJ N,SAKUL W,GARCIA-SEGURAS,et al..Implementation of fluidized-bed Fenton as pre-treatment to reduce chemical oxygen demand of wastewater from screw manufacture:Influence of reagents feeding mode[J].Separation and Purification Technology,2018,20 (2):275-280．
[7] NAKAGAWA H,YAMAGUCHI E.Influence of oxalic acid formed on the degradation of phenol by Fenton reagent[J].Chemosphere,2012,88(2):183-187．
[8] 曾婧．Fenton试剂处理含苯胺废水的研究[J]．江西化工,2019,22(3):70-72．
[9] ZAZO J A,PLIEGO G,BLASCO S,et al.Intensification of the Fenton process by increasing the temperature[J].Industrial&Engineering Chemistry Research,2011,50(2):866-870．
[10] LEE H,LEE H J,SEDLAK D L,et al.pH-Dependent reactivity of oxidants formed by iron and copper-catalyzed decomposition of hydrogen peroxide[J].Chemosphere,2013,92(6):652-658．
[11] MAEKAWA J,MAE K,NAKAGAWA H.Fenton-Cu2+system for phenol mineralization[J].Environmental Chemical Engineering,2014,2(3):1275-1280．
[12] LEE H,SEONG J,LEE KI,Kim Hak-Hyeon,Choi Jaemin,Kim Jae-Hong,Lee Changha.Chloride-enhanced oxidation of organic contaminants by Cu(II)-catalyzed Fentonlike reaction at neutral pH.[J].Journal of hazardous materials,2018,344(15):1174-1180．
[13] 武家玉,李镇镇．类芬顿体系降解苯酚[J]．山西化工,2017,37(6):21-23．
[14] SARMENTO A P,BORGES A C,DE MATOS A T,et al.Phenol degradation by Fenton-like process[J].Environmental Science and Pollution Research,2016,23(18):18429-18438．
[15] DINARVAND M,SOHRABI M,ROYAEE S J,et al.Degradation of heterogeneous Fenton process in an impinging streams reactor with catalyst bed[J].Asia-Pacific Journal of Chemical Engineering,2017,12(4):631-639．
[16] SHAO Y,CHEN H.Heterogeneous Fenton oxidation of phenol in fixed-bed reactor using Fe nanoparticles embedded within ordered mesoporous carbons[J].Chemical Engineering Research and Design,2018,132(4):57-68．
[17] HOU L W,ZHANG Q H,Franois Jrme,et al.Shapecontrolled nanostructured magnetite-type materials as highly efficient Fenton catalysts[J].Applied Catalysis B:Environmental,2014,144(1):739-749．
[18] WANG J,YAO Z,WANG Y,et al.Preparation of immobilized coating Fenton-like catalyst for high efficient degradation of phenol[J].Environmental Pollution,2017,224 (3):552-558．
[19] WANG Y B,ZHAO H Y,ZHAO G H.Iron-copper bimetallic nanoparticles embedded within ordered mesoporous carbon as effective and stable heterogeneous Fenton catalyst for the degradation of organic contaminants[J].Applied Catalysis,B.Environmental:An International Journal Devoted to Catalytic Science and Its Applications,2015,164 (3):396-406．
[20] GAO P,SONG Y,HAO M,et al.An effective and magnetic Fe 2O3-ZrO 2catalyst for phenol degradation under neutral pH in the heterogeneous Fenton-like reaction[J].Separation&Purification Technology,2018,201(8):238-243．
[21] WANG H,JING M M,WU Y,et al.Effective degradation of phenol via Fenton reaction over CuNiFe layered double hydroxides[J].Journal of hazardous materials,2018,353(7):53-61．
[22] BABA Y,YATAGAI T,HARADA T,et al.Hydroxyl radical generation in the photo-Fenton process:Effects of carboxylic acids on iron redox cycling[J].Chemical Engineering Journal,2015,277(10):229-241．
[23] GANIYU S O,ZHOU M,MARTíNEZ-HUITLE C A.Heterogeneous electro-Fenton and photoelectro-Fenton processes:A critical review of fundamental principles and application for water/wastewater treatment[J].Applied Catalysis B:Environmental,2018,235(11):103-129．
[24] PARK J,MOON G H,SHIN K,et al.Oxalate-TiO 2complex-mediated oxidation of pharmaceutical pollutants through ligand-to-metal charge transfer under visible light[J].Chemical Engineering Journal,2018,343(7):689-698．
[25] GIANNAKIS S,POLO-LOPEZ M I,SPUHLER D,et al.Solar disinfection is an augmentable,in situ-generated photoFenton reaction-Part 1:A review of the mechanisms and the fundamental aspects of the process[J].Applied Catalysis BEnvironmental,2016,199(15):199-223．
[26] MANENTI D R,SOARES P A,SILVA T F C V,et al.Performance evaluation of different solar advanced oxidation processes applied to the treatment of a real textile dyeing wastewater[J].Environmental Science&Pollution Research,2015,22(2):833-845．
[27] QIAN X,REN M,ZHU Y,et al.Visible light assisted heterogeneous Fenton-like degradation of organic pollutant viaα-FeOOH/Mesoporous carbon composites[J].Environmental Science&Technology,2017,51(7):3993-4000．
[28] NAHID H,AYOUB K J.Comparison of photo-Fenton,O3/H2O2/UV and photocatalytic processes for the treatment of gray water[J].Ecotoxicology and Environmental Safety,2018,161:683-690．
[29] AMBIKA S,DEVASENA M,NAMBI I M.Assessment of meso scale zero valent iron catalyzed Fenton reaction in continuous-flow porous media for sustainable groundwater remediation[J].Chemical Engineering Journal,2018,334(2):264-272．
[30] YOON I H,YOO G,HONG H J,et al.Kinetic study for phenol degradation by ZVI-assisted Fenton reaction and related iron corrosion investigated by X-ray absorption spectroscopy[J].Chemosphere,2016,145(1):409-415．
[31] JosAlejandro Ortega-Mndez,JosAlberto Herrera-Melin,Javier Araa,et al.Performance and Economic Assessment of the Treatment of Phenol with TiO2Photocatalysis,PhotoFenton,Biological Aerated Filter,and Wetland Reactors[J].Chemical Engineering&Technology,2017,40 (6):1165-1175．
[32] PLIEGO G,GARCIA-MU1OZ P,ZAZO J A,et al.Improving the Fenton process by visible LED irradiation[J].Environmental Science and Pollution Research,2016,23(23):23449-23455．
[33] Mohamed Gar Alalm,Ahmed Tawfik,Shinichi Ookawara.Investigation of optimum conditions and costs estimation for degradation of phenol by solar photo-Fenton process[J].Applied Water Science,2017,1(7):375-382．
[34] NOGUEIRA K R B,NASCIMENTO C A O,GUARDANIR,et al..Teixeira.Feasibility study of a solar reactor for phenol treatment by the photo-fenton process in aqueous solution[J].Chemical Engineering&Technology,2012,35(12):2125-2132．
[35] HUANG Y H,HUANG Y J,TSAI H C,et al.Degradation of phenol using low concentration of ferric ions by the photoFenton process[J].Journal of the Taiwan Institute of Chemical Engineers,2010,41(6):699-704．
[36] Syllos Santos da Silva,Osvaldo Chiavone-Filho,Eduardo L.de Barros Neto,et alEffect of Inorganic Salt Mixtures on Phenol Mineralization by Photo-Fenton-Analysis via an Experimental Design[J].Water Air and Soil Pollution,2014,225(1):1-10．
[37] MOFRAD M R,NEZHAD M E,AKBARI H,et al.Evaluation of Efficacy of Advanced Oxidation Processes Fenton,Fenton-like and Photo-Fenton for Removal of Phenol from A-queous Solutions[J].Journal Chemical Society of Pakistan,2015,37(2):266-271．
[38] LIU Y Y,Xuemin,et al.Alignedα-FeOOH nanorods anchored on a graphene oxide-carbon nanotubes aerogel can serve as an effective Fenton-like oxidation catalyst[J].Applied Catalysis B Environmental,2017,213(9):74-86．
[39] DEMARCHIS L,MINELLA M,NISTICòR,et al.PhotoFenton reaction in the presence of morphologically controlled hematite as iron source[J].Journal of Photochemistry&Photobiology A Chemistry,2017,307-308(7-8):99-107．
[40] Lv,Qiang,Lu,et al.Preparation of magnetic zeolite gammaFe2O3/TS-1 with core/shell structure and application in photocatalytic degradation[J].Microporous&Mesoporous Materials,2015,203(2):202-207．
[41] Len,María Andrea De,Rodríguez,Mayra,Marchetti S G,et al.Raw montmorillonite modified with iron for photoFenton processes:influence of iron content on textural,structural and catalytic properties[J].Journal of Environmental Chemical Engineering,2017,5 (5):4742-4750．
[42] Sun,Kai,Changgeng.Controllable synthesis of coralloid Fe3O4nanoclusters in an ionic liquid for catalytic applications[J].Crystengcomm,2016,18(5):714-720．
[43] ZHANG S,LIANG S,WANG X,et al.Trinuclear iron cluster intercalated montmorillonite catalyst:Microstructure and photo-Fenton performance[J].Catalysis Today,2011,175(1):362-369．
[44] PARIDA K M,PRADHAN A C.Femeso-Al2O3:An Efficient Photo-Fenton Catalyst for the Adsorptive Degradation of Phenol[J].Industrial&Engineering Chemistry Research,2010,49(18):8310-8318．
[45] 刘保锋,王丽,童晨．树脂负载Fe(Ⅲ)/Cu(Ⅱ)非均相光Fenton体系降解罗丹明B模拟废水研究[J]．湖北农业科学,2017,56(18):3461-3467．
[46] 王维明,张冉,王树涛,等．非均相光降解-氯酚的研究[J]．安全与环境学报,2013,13(1):31-35．
[47] LIANG C,LIU Y,LI K,et al.Heterogeneous photo-Fenton degradation of organic pollutants with amorphous Fe-Znoxide/hydrochar under visible light irradiation[J].Separation&Purification Technology,2017,188(7):105-111．
[48] SANTOS A J D,LIMA M D D,SILVA D R D,et al.Influence of the water hardness on the performance of electro-Fenton approach:Decolorization and mineralization of Eriochrome Black T[J].Electrochimica Acta,2016,208(8):156-163．
[49] MOREIRA F C,BOAVENTURA R A R,BRILLAS E,et al.Electrochemical advanced oxidation processes:A review on their application to synthetic and real wastewaters[J].Applied Catalysis B Environmental,2016,202(4):217-261．
[50] XIA G,LU Y,XU H.Electrogeneration of hydrogen peroxide for electro-Fenton via oxygen reduction using polyacrylonitrile-based carbon fiber brush cathode[J].Electrochimica Acta,2015,158(Complete):390-396．
[51] MOUSSET E,WANG Z,HAMMAKER J,et al.Physicochemical properties of pristine graphene and its performance as electrode material for electro-Fenton treatment of wastewater[J].Electrochimica Acta,,2016,214 (10):217-230．
[52] MOUSSET E,WANG Z,HAMMAKER J,et al.Electrocatalytic phenol degradation by a novel nanostructured carbon fiber brush cathode coated with graphene ink[J].Electrochimica Acta,2017,258(20):607-617．
[53] DENG F,GARCIA-RODRIGUEZ O,OLVERA-VARGASH,et al.Iron-foam as a heterogeneous catalyst in the presence of tripolyphosphate electrolyte for improving electro-Fenton oxidation capability[J].Electrochimica Acta,2018,272(10):176-183．
[54] DENG F,OLVERA-VARGAS H,GARCIA-RODRIGUEZO,et al.The synergistic effect of nickel-iron-foam and tripolyphosphate for enhancing the electro-Fenton process at circum-neutral pH[J].Chemosphere,2018,201(6):687-696．
[55] 陈婷,冯波,梁静．超声波协同紫外光催化Fenton反应法降解对氯苯酚废水[J]．基因组学与应用生物学,2013,0(3):379-383．
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Research progress of Fenton reagent catalytic degradation of organic wastewater
Abstract: As an advanced oxidation technology(AOPs),Fenton technology has great advantages in the field of degrading organic pollutants in wastewater,which is a very ideal organic sewage treatment process.In addition,it is based on the general Fenton technology.Compared with the traditional Fenton technology,the Fenton-like technology,electric Fenton technology(EF),photo Fenton technology,etc.,also have their own improvements.This article reviews the catalytic mechanism,influencing factors,technical obstacles,technological breakthroughs,and latest research trends of Fenton and Fenton-like,electric Fenton,and photo Fenton technologies.
Keywords: Fenton reagent; Catalytic degradation; Mechanism; Organic matter Oxidation; Water treatment;
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